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The boiling point of water at standard atmospheric pressure is 212°F. This is a well-established fact in the field of thermodynamics and is critical for understanding various applications in boiler operation, where steam generation is essential.

When water reaches this temperature, it changes from a liquid state to a gaseous state, enabling it to produce steam, which can then be used for heating, powering turbines, or other industrial purposes. It's important to note that the boiling point can vary depending on the atmospheric pressure; for instance, at higher altitudes where pressure is lower, water will boil at a temperature less than 212°F.

Understanding this temperature is vital in boiler operation since maintaining the correct temperature is crucial for efficiency and safety in these systems. The other temperatures listed do not represent the boiling point of water under normal conditions, highlighting why the knowledge of 212°F is essential for boiler operators.